Some info on man made fibres (fibers :) ) taken from a webpage on fabric identification (i.e. burning properties)
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Acetate is made from cellulose (wood fibers), technically cellulose acetate. Acetate burns readily with a flickering flame that cannot be easily extinguished. The burning cellulose drips and leaves a hard ash. The smell is similar to burning wood chips.
Acrylic technically acrylonitrile is made from natural gas and petroleum. Acrylics burn readily due to the fiber content and the lofty, air filled pockets. A match or cigarette dropped on an acrylic blanket can ignite the fabric which will burn rapidly unless extinguished. The ash is hard. The smell is acrid or harsh.
Nylon is a polyamide made from petroleum. Nylon melts and then burns rapidly if the flame remains on the melted fiber. If you can keep the flame on the melting nylon, it smells like burning plastic.
Polyester is a polymer produced from coal, air, water, and petroleum products. Polyester melts and burns at the same time, the melting, burning ash can bond quickly to any surface it drips on including skin. The smoke from polyester is black with a sweetish smell. The extinguished ash is hard.
Rayon is a regenerated cellulose fiber which is almost pure cellulose. Rayon burns rapidly and leaves only a slight ash. The burning smell is close to burning leaves.
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